The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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Contact, Imprint, Acknowledgements

When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Peroxy radicals / Alkylperoxy / CH3O2 / JPL-97(1997)_298K_210-290nm(rec)

DATAFILE: CH3O2_JPL-97(1997)_298K_210-290nm(rec).txt
NAME: methylperoxy radical
FORMULA: CH3O2
AUTHOR(YEAR): JPL-97(1997)
T: 298K
λ: 210-290nm(rec)
BIBLIOGRAPHY: W.B. DeMore, S.P. Sander, D.M. Golden, R.F. Hampson, M.J. Kurylo, C.J. Howard, A.R. Ravishankara, C.E. Kolb, and M.J. Molina, "Chemical Kinetics and Photochemical Data for Use in Stratospheric Modeling. Evaluation Number 12", JPL Publication 97-4, Jet Propulsion Laboratory, Pasadena, 1997; https://jpldataeval.jpl.nasa.gov/pdf/Atmos97
COMMENTS: JPL-97 recommendation:

The cross section at 250 nm was set to 4.00×10-18 cm2 molecule-1 to which the spectrum was scaled; average values were taken of those recommended by

P.D. Lightfoot, R.A. Cox, J.N. Crowley, M. Destriau, G.D. Hayman, M.E. Jenkin, G.K. Moortgat, and F. Zabel, "Organic peroxy radicals: Kinetics, spectroscopy and tropospheric chemistry," Atmos. Environ. 26A, 1805-1961 (1992); DOI: 10.1016/0960-1686(92)90423-I , and

T.J. Wallington, P. Dagaut, and M.J. Kurylo, "Ultraviolet absorption cross sections and reaction kinetics and mechanisms for peroxy radicals in the gas phase," Chem. Rev. 92, 667-710 (1992); DOI: 10.1021/cr00012a008

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